Ultrasonic-promoted rapid preparation of PVC/TiO2-BSA nanocomposites: Characterization and photocatalytic degradation of methylene blue

Abstract

In the present project in order to prevent agglomeration and better dispersion of TiO₂ nanoparticles (NPs) in the poly(vinyl chloride) (PVC) matrix, initially, the surface of TiO₂ NPs was covered by bovine serum albumin protein (BSA) via sonication method. Then, the TiO₂-BSA powders were embedded into the PVC matrix using ultrasonic irradiations. With mechanical and magnetic stirring homogenous mixture was not obtained. So sonication process was very essential and vital. Physical, chemical and structural properties of the samples were investigated with various tools. Morphology studies showed the well distribution of spherical TiO₂ NPs in the PVC matrix. TGA analysis showed that nanocomposites (NCs) have higher thermal stability than the pristine polymer. The photocatalytic activity tests by destroying the methylene blue dye on the pristine TiO₂ NPs, TiO₂-BSA NPs and PVC/TiO₂-BSA NC 6 wt% were examined. The results showed that the photocatalytic activity of TiO₂ NPs was reduced in the presence of BSA and PVC. It can be concluded that the TiO₂-BSA NPs and PVC/TiO₂-BSA NC 6 wt% have UV shielding properties and can protect film from degradation by UV.